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Inovasi Teknologi Konversi Biomassa Lignoselulosa sebagai Sumber Energi Terbarukan dan Bahan Kimia Berkelanjutan
Keywords:
Inovasi Teknologi, Biorefinery, Biomassa, Selulosa, Bioetanol, Selulosa asetatSynopsis
Orasi ini berfokus pada pengembangan senyawa berbasis biomassa lignoselulosa sebagai sumber energi terbarukan dan bahan kimia berkelanjutan. Pengembangan ini menawarkan prospek yang menjanjikan untuk masa depan serta mendukung pencapaian Sustainable Development Goals (SDGs), khususnya dalam bidang energi bersih, industri berkelanjutan, dan perubahan iklim. Dengan inovasi dalam teknologi pemrosesan, pengembangan senyawa berbasis lignoselulosa tidak hanya membuka peluang ekonomi hijau tetapi juga mendorong transformasi industri menuju masa depan yang lebih ramah lingkungan.
Ada tiga poin penting yang dibahas dalam orasi ini. Pertama, tahap perlakuan awal pada biomassa. Tahap ini sangat penting sebelum biomassa dikonversi menjadi produk bernilai tinggi, seperti bioetanol, dissolving pulp, selulosa asetat, dan senyawa turunan lignin. Teknologi perlakuan awal yang berkembang saat ini, seperti metode fisik, kimia, biologis serta kombinasinya, membuka peluang untuk meningkatkan efisiensi proses delignifikasi.
Kedua, jumlah lignin di dalam proses delignifikasi. Lignin telah diketahui menjadi faktor penting yang menentukan efektivitas pemisahan komponen biomassa. Selain itu, ternyata jenis monomer penyusunnya memainkan peran penting dalam pemisahan dan konversi biomassa. Proses penghilangan residual lignin dengan metode bleaching menggunakan Totally Chlorine Free (TCF) merupakan langkah lanjut dari proses Elementary Chlorine Free (ECF) dan menawarkan solusi yang lebih ramah lingkungan untuk ekstraksi selulosa.
Ketiga, pemilihan reaktor yang tepat. Hal ini sangat penting untuk memastikan efisiensi, kualitas produk, dan pengendalian proses yang optimal. Reaktor portabel skala laboratorium untuk menurunkan kadar lignin secara pararel pada beberapa biomassa dan reaktor pretreatment kontinu yang menggunakan sistem screw ekstruksi merupakan state of the art naskah orasi ini.
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References
Aji, E. T., Hasanudin, H., Das, A. K., & Maryana, R. (2024). Efficient integrated production of bioethanol and lignin from oil palm empty fruit bunch biomass using chemical steam explosion method. Biomass Conversion and Biorefinery, 0123456789. https://doi.org/10.1007/s13399-024-06058-3
Aprobi. (2024). Bioetanol: Perjalanan Bahan Bakar Masa Depan. https://www.aprobi.or.id/bioetanol-perjalanan-bahan-bakar-masa-depan/
Ariyanti, D., Adi Sasongko, N., Maryana, R., Agung Nugroho, R., Thamrin, S., Rimantho, D., Wahyono, Y., Kumar Das, A., Yansa Garia, O., & Tayon, F. (2024). Alkaline pretreatment of Durio sp. residual biomass enhances cellulose accessibility for efficient bioethanol production. International Journal of Ambient Energy, 45(1). https://doi.org/10.1080/01430750.2024.2378016
Cheah, W. Y., Sankaran, R., Show, P. L., Ibrahim, T. N. B. T., Chew, K. W., Culaba, A., & Jo-Shu, C. (2020). Pretreatment methods for lignocellulosic biofuels production: current advances, challenges and future prospects. Biofuel Research Journal, 7(1), 1115.
Dahnum, D., Agustian, E., Triwahyuni, E., Kristiani, A., Maryana, R., & Sudiyani, Y. (2022). Functionalized Alkaline Lignin for Removal of Lead in Aqueous Solution. Jurnal Kimia Sains Dan Aplikasi, 25(5), 192–196. https://doi.org/10.14710/jksa.25.5.192-196
Dani, S., & Wibawa, A. (2018). Challenges and policy for biomass energy in Indonesia. International Journal of Business, Economics and Law.
Elliston, A., Wilson, D. R., Wellner, N., Collins, S. R. A., Roberts, I. N., & Waldron, K. W. (2015). Bioresource Technology Effect of steam explosion on waste copier paper alone and in a mixed lignocellulosic substrate on saccharification and fermentation. Bioresource Technology, 187, 136–143. https://doi.org/10.1016/j.biortech.2015.03.089
Erin Voegele. (2024). Raizen celebrates opening of new cellulosic ethanol plant. Ethanol Producer Magazine. https://ethanolproducer.com/articles/raizen-celebrates-opening-of-new-cellulosic-ethanol-plant
Francisco, M., Van Den Bruinhorst, A., & Kroon, M. C. (2012). New natural and renewable low transition temperature mixtures (LTTMs): Screening as solvents for lignocellulosic biomass processing. Green Chemistry, 14(8), 2153–2157. https://doi.org/10.1039/c2gc35660k
Haldar, D., & Purkait, M. K. (2021). A review on the environment-friendly emerging techniques for pretreatment of lignocellulosic biomass: Mechanistic insight and advancements. Chemosphere, 264, 128523. https://doi.org/10.1016/j.chemosphere.2020.128523
Han, M., Kang, K. E., Kim, Y., & Choi, G. W. (2013). High efficiency bioethanol production from barley straw using a continuous pretreatment reactor. Process Biochemistry, 48(3), 488–495. https://doi.org/10.1016/j.procbio.2013.01.007
Harsono, H., Putra, A. S., Maryana, R., Rizaluddin, A. T., H’ng, Y. Y., Nakagawa-izumi, A., & Ohi, H. (2016). Preparation of dissolving pulp from oil palm empty fruit bunch by prehydrolysis soda-anthraquinone cooking method. Journal of Wood Science, 62(1). https://doi.org/10.1007/s10086-015-1526-3
Indonesia, C. (2023). Konsumsi Kertas Dunia Diramal Tembus Rp6.000 T, Ini Pemicunya. 2023. https://www.cnbcindonesia.com/news/20231006105116-4-478447/konsumsi-kertas-dunia-diramal-tembus-rp6000-t-ini-pemicunya
Irawan, Y., Ramdani, D., Maryana, R., Triwahyuni, E., Muryanto, M., Bardant, T. B., & Sudiyani, Y. (2021). REAKTOR KONTINU TIPE ULIR DENGAN PEMANAS JAKET GANDA UNTUK DELIGNIFIKASI (P00202107075).
Jacquet, N., Maniet, G., Vanderghem, C., Delvigne, F., & Richel, A. (2015). Application of Steam Explosion as Pretreatment on Lignocellulosic Material: A Review. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie503151g
Jeon, H., Kang, K. E., Jeong, J. S., Gong, G., Choi, J. W., Abimanyu, H., Ahn, B. S., Suh, D. J., & Choi, G. W. (2014). Production of anhydrous ethanol using oil palm empty fruit bunch in a pilot plant. Biomass and Bioenergy, 67, 99–107. https://doi.org/10.1016/j.biombioe.2014.04.022
Karunanithy, C., & Muthukumarappan, K. (2011). Optimization of alkali soaking and extrusion pretreatment of prairie cord grass for maximum sugar recovery by enzymatic hydrolysis. Biochemical Engineering Journal, 54(2), 71–82. https://doi.org/10.1016/j.bej.2011.02.001
Maryana, R., Anwar, M., Suwanto, A., Hasanah, S. U., & Fitriana, E. (2020). Comparison Study of Various Cellulose Acetylation Methods from its IR Spectra and Morphological Pattern of Cellulose Acetate as a Biomass Valorisation. https://pdfs.semanticscholar.org/8fa3/b9f2aeb656dc0cb1ec4ebca143580709dccd.pdf
Maryana, R., Anwar, M., Hasanah, S. U., Fitriana, E., Suwanto, A., & Rizal, W. A. (2020). Cellulose acetate production from paddy rice straw and oil palm empty fruit bunch : trichloroacetate catalyst. IOP Conference Series: Earth and Environmental Science, 462. https://doi.org/10.1088/1755-1315/462/1/012054
Maryana, R., Bardant, T. B., Ihsan, D. M., Das, A. K., Irawan, Y., Rizal, W. A., Triwahyuni, E., Muryanto, Utami, A. R. I., & Sudiyani, Y. (2022). Reducing sugars and bioethanol production from oil palm empty fruit bunch by applying a batch and continuous pretreatment process with low temperature and pressure. Biomass Conversion and Biorefinery, 0123456789. https://doi.org/10.1007/s13399-022-03138-0
Maryana, R., Bardant, T. B., & Muryanto, M. (2023). Lignin isolation and characterization as co-products from pilot plants of second generations bioethanol Lignin Isolation and Characterization as Co-Products from Pilot Plants of Second Generations Bioethanol. 040016(March).
Maryana, R., Bardant, T. B., Santi, E. L., Triwahyuni, E., Muryanto, Oktaviani, & Dahnum, D. (2022). Bioethanol production process with SHF method from EFBs pulp and its microcrystalline. IOP Conference Series: Earth and Environmental Science, 1108(1). https://doi.org/10.1088/1755-1315/1108/1/012021
Maryana, R., Bardant, T. B., Umam, E. F., Irawan, Y., Triwahyuni, E., Muryanto, Dahnum, D., Hada Putri, A. M., Rinaldi, N., Oktaviani, Prasetyo, J., & Sudiyani, Y. (2023). Lignin Isolation from both Soluble and Insoluble Material of Soda Black Liquor. AIP Conference Proceedings, 2902(1). https://doi.org/10.1063/5.0173137
Maryana, R., Dahnum, D., Triwahyuni, E., Muryanto, M., Bardant, T. B., Das, A. K., Rizal, W. A., Oktaviani, O., & Sudiyani, Y. (2024). Synthesis of lignin- amine from the waste of pilot plant bioethanol as a green bioadsorbent for lead removal R. International Journal of Environmental Science and Technology. https://doi.org/https://doi.org/10.1007/s13762-024-06026-4
Maryana, R., Ma’rifatun, D., Wheni, I. A., K.w., S., & Rizal, W. A. (2014). Alkaline pretreatment on sugarcane bagasse for bioethanol production. Energy Procedia, 47, 250–254.
Maryana, R., Muryanto, M., Irawan, Y., Triwahyuni, E., Bardant, T. B., & Sudiyani, Y. (2023). PROSES DELIGNIFIKASI TANDAN KOSONG SAWIT SECARA KONTINU MENGGUNAKAN REAKTOR ULIR SEBAGAI BAHAN BAKU PRODUKSI BIOETANOL (S00202308267).
Maryana, R., Muryanto, Triwahyuni, E., Bardant, T., Y, I., & Sudiyani, Y. (2021). Potency and Challenges in The Commersialisation of Bioethanol First and Second Generation in Indonesia. The 5th SATREPS Conference, May, 79–84. https://publikasikr.lipi.go.id/index.php/satreps/article/view/643/592
Maryana, R., Muryanto, Triwahyuni, E., Oktaviani, O., Prasetia, H., Das, A. K., & Sudiyani, Y. (2022). Extraction of Cellulose Acetate from Cajuput (Melaleuca leucadendron) Twigs and Sugarcane (Saccharum officinarum) Bagasse by Environmentally Friendly Approach. Waste and Biomass Valorization, 13(3), 1535–1545. https://doi.org/10.1007/s12649-021-01610-y
Maryana, R., Nakagawa-izumi, A., Kajiyama, M., & Ohi, H. (2017). Environment-Friendly Non-Sulfur Cooking and Totally ChlorineFree Bleaching for Preparation of Sugarcane Bagasse Cellulose. Journal of Fiber Science and Technology, 73(8), 182–191. https://doi.org/10.2115/fiberst.2017-0025
Maryana, R., Nakagawa-izumi, A., Ohi, H., & Nakamata, K. (2017). Dependence of Enzymatic Saccharification on Residual Lignin Structure in Sugarcane. Japan Tappi Journal, 71(6), 679–687. https://doi.org/10.2524/jtappij.1608
Maryana, R., Oktaviani, K., Tanifuji, K., & Ohi, H. (2014). Comparison-between-Acid-Sulfite-and-Soda-AQ-Delignification-Methods-for-Effective-Bio-ethanol-Production-from-Sugarcane-Bagasse-and-Oil-Palm-Empty-Fruit-Bunch.pdf. Pan Pacific Conference, 7. https://www.researchgate.net/profile/Roni-Maryana/publication/262646680_Comparison_between_Acid_Sulfite_and_Soda-AQ_Delignification_Methods_for_Effective_Bio-ethanol_Production_from_Sugarcane_Bagasse_and_Oil_Palm_Empty_Fruit_Bunch/links/0a85e5385b0d8e4b5d
Maryana, R., Rizal, W. A., & et al. (2019). REAKTOR PORTABEL SKALA LABORATORIUM UNTUK MENURUNKAN KADAR LIGNIN DARI BIOMASSA (S00201911243).
Maryana, R., Triwahyuni, E., Muryanto, M., Oktaviani, O., & et al. (2024). Current Progress on Biomass Pretreatment: The Key for Its Valorization. In Biomass Conversion and Biorefinery (Vol. 12, Issue 10). https://doi.org/10.1007/978-981-99-7769-7
Maryana, R., & Wahono, S. K. (2009). Production and purification of bioethanol from molasses and cassava. AIP Conference Proceedings, 1169. https://doi.org/10.1063/1.3243248
Maryana, R., & Wahono, S. K. (2012). Bioethanol potency: Development of small business based on cassava in Gunungkidul region, Yogyakarta. October, 16–18.
Muryanto, M., Sudiyani, Y., Darmawan, M. A., Handayani, E. M., & Gozan, M. (2023). Simultaneous Delignification and Furfural Production of Palm Oil Empty Fruit Bunch by Novel Ternary Deep Eutectic Solvent. Arabian Journal for Science and Engineering, 48(12), 16359–16371. https://doi.org/10.1007/s13369-023-08211-y
Muryanto, Wahyuni, E. T., Abimanyu, H., Cahyono, A., Cahyono, E. T., & Sudiyani, Y. (2015). Alkaline delignification of oil palm empty fruit bunch using black liquor from pretreatmnet. Procedia Chemistry, 16, 99–105. https://doi.org/10.1016/j.proche.2015.12.032
Nguyen, T.-A. D., Kim, K.-R., Han, S. J., Cho, H. Y., Kim, J. W., Park, S. M., Park, J. C., & Sim, S. J. (2010). Pretreatment of rice straw with ammonia and ionic liquid for lignocellulose conversion to fermentable sugars. Bioresource Technology, 101(19), 7432–7438. https://doi.org/10.1016/j.biortech.2010.04.053
Oktaviani, O., Yunus, A. L., Bic, M. Y. Y., Rahmaena, I. J., Nuryanthi, N., Syahputra, A. R., Maryana, R., & Rahmawati, R. (2024). Study of potential antioxidant of irradiated lignin. AIP Conference Proceedings, 3053(1). https://doi.org/10.1063/5.0199789
Pena-Pereira, F., & Namiesnik, J. (2014). Ionic liquids and deep eutectic mixtures: Sustainable solvents for extraction processes. ChemSusChem, 7(7), 1784–1800. https://doi.org/10.1002/cssc.201301192
Perindustrian, K. (2018). Diversifikasi Pulp Bakal Pangkas Impor US$ 500 Juta. 22 January 2018. https://www.kemenperin.go.id/artikel/18681/Diversifikasi-Pulp-Bakal-Pangkas-Impor-US$-500-Juta
Prasetyo, J., Dahnum, D., Murti, G. W., Sugiarto, A. T., Maryana, R., & Machsun, A. L. (2023). Delignification of Palm Oil Empty Fruit Bunch by ozonization and its physicochemical effect. Biomass Conversion and Biorefinery, 14(13), 13721–13730. https://doi.org/10.1007/s13399-022-03719-z
Rimantho, D., Ariyanti, D., & Maryana, R. (2024). Environmentally Friendly Strategies for Recycling Agricultural Waste to Produce Renewable Energy: A Case Study of Durian Fruit. Decision Making: Applications in Management and Engineering, 7(2), 294–312. https://doi.org/10.31181/dmame7220241138
Salaghi, A., Putra, A. S., Maryana, R., Kajiyama, M., & Ohi, H. (2018). Preparation of Dissolving Pulp by Totally Chlorine-free Bleaching : Roles of Hardwood Syringyl and Guaiacyl Lignins. Japan Tappi Journal, 72(10), 1167–1175. https://doi.org/10.2524/jtappij.72.1167
Statistik, B. P. (2023). Statistik Kelapa Sawit Indonesia 2022 (05100.2312). https://www.bps.go.id/id/publication/2023/11/30/160f211bfc4f91e1b77974e1/statistik-kelapa-sawit-indonesia-2022.html
Statistik, B. P. (2024a). Data Ekspor Impor Nasional. https://www.bps.go.id/id/exim
Statistik, B. P. (2024b). Luas Kawasan Hutan dan Kawasan Konservasi Perairan Indonesia Berdasarkan Surat Keputusan Menteri Lingkungan Hidup dan Kehutanan, 2017-2022. 2024. https://www.bps.go.id/id/statistics-table/1/MTcxNiMx/luas-kawasan-hutan-dan-kawasan-konservasi-perairan-indonesia-berdasarkan-surat-keputusan-menteri-lingkungan-hidup-dan-kehutanan--2017-2022.html
Statistik, B. P. (2024c). Luas Panen, Produksi, dan Produktivitas Padi Menurut Provinsi, 2021-2023. 1 March 2024. https://www.bps.go.id/id/statistics-table/2/MTQ5OCMy/luas-panen--produksi--dan-produktivitas-padi-menurut-provinsi.html
Statistik, B. P. (2024d). Volume Ekspor dan Impor Migas (Berat bersih: ribu ton) 1996-2023. https://www.bps.go.id/id/statistics-table/1/MTAwMyMx/volume-ekspor-dan-impor-migas--berat-bersih-ribu-ton--1996-2023.html
Sudiyani, Y., Styarini, D., Triwahyuni, E., Sudiyarmanto, Sembiring, K. C., Aristiawan, Y., Abimanyu, H., & Han, M. H. (2013). Utilization of biomass waste empty fruit bunch fiber of palm oil for bioethanol production using pilot - Scale unit. Energy Procedia, 32, 31–38. https://doi.org/10.1016/j.egypro.2013.05.005
Sudiyani, Y., Syahrul, A., & Mansur, D. (2019). Perkembangan Bioetanol G2: Teknologi dan Perspektif. Lipi Press, 2019.
Sudiyani, Y., Triwahyuni, E., Sugiwati, S., Maryana, R., Muryanto, Bardant, T. B., & Fitriady, M. A. (2024). TRANSISI ENERGI: MERACIK FORMULA INOVATIF ETANOL UNTUK MASA DEPAN TERANG. Buletin Pertamina Energi Institute, 93–106. https://www.pertamina.com///Media/File/Buletin PEI Vol 10 No 1 Tahun 2024 (ONLINE).pdf
Sudiyani, Y., Waluyo, J., Triwahyuni, E., Burhani, D., Muryanto, Primandaru, P., Riandy, A. P., & Novia, N. (2017). Optimization pretreatment condition of sweet sorghum bagasse for production of second generation bioethanol. AIP Conference Proceedings, 1803. https://doi.org/10.1063/1.4973142
Sun, Y., & Cheng, J. (2002). Hydrolysis of lignocellulosic materials for ethanol production : a review q. Bioresource Technology, 83(1), 1–11. https://doi.org/10.1016/S0960-8524(01)00212-7
Triwahyuni, E., Miftah, A. K., Muryanto;, Maryana, R., & Sudiyani, Y. (2021). Effect of CO2-added Steam Explosion on Oil Palm Empty Fruit Bunch for Bioethanol Production. CELLULOSE CHEMISTRY AND TECHNOLOGY, 55(7–8), 839–847.
Triwahyuni, E., Miftah, A. K., Muryanto, M., Maryana, R., & Sudiyani, Y. (2023). Conversion of oil palm empty fruit bunch into bioethanol through pretreatment with CO2 as impregnating agent in alkali explosion. Biomass Conversion and Biorefinery, 452. https://doi.org/10.1007/s13399-023-04102-2
UNCTAD. (2016). Second generation biofuel markets. Second Generation Biofuel Markets:State of Play, Trade and Developing Country Perspectives, 1–69. https://unctad.org/publication/second-generation-biofuel-markets-state-play-trade-and-developing-country-perspectives
Utami, A. R. I., Sugiwati, S., Maryana, R., Darus, L., Mel, M., Maulidin, I., Erawan, F., Yupaldi, N., & Zhafran, A. L. (2025). Predictive Modelling of Ethanol Production from Biomass Pretreated with Ionic Liquids Using SuperPro Designer. Journal of Physics: Conference Series 2942 012048, 1–8. https://iopscience.iop.org/article/10.1088/1742-6596/2942/1/012048/pdf
Wang, K., Chen, J., Sun, S., & Sun, R. (2015). Steam Explosion. In Pretreatment of Biomass. Elsevier B.V. https://doi.org/10.1016/B978-0-12-800080-9.00006-2
Zhao, L., Sun, Z. F., Zhang, C. C., Nan, J., Ren, N. Q., Lee, D. J., & Chen, C. (2022). Advances in pretreatment of lignocellulosic biomass for bioenergy production: Challenges and perspectives. Bioresource Technology, 343(October 2021), 126123. https://doi.org/10.1016/j.biortech.2021.126123
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