Pengembangan Nanokomposit Berbasis Nanoselulosa dan Nanokarbon sebagai Material Fungsional

Authors

Rike Yudianti
Badan Riset dan Inovasi Nasional

Keywords:

Nanokomposit, Nanoselulosa, Nanokarbon, Material Fungsiona

Synopsis

Nanokomposit berbasis nanokarbon berpotensi menghasilkan produk yang lebih inovatif dan unggul. Carbon Nanotube (CNT) merupakan salah satu nanokarbon berstruktur selimut heksagonal karbon dan berbentuk tubular dengan susunan atom karbon paralel dengan arah tubularnya. Keunggulan karakteristik intrinsik dari CNT melahirkan karakteristik unik seperti sifat elektronik, optik, dan magnetik yang tidak ditemukan di nanoselulosa. CNT berukuran 1–100 nm tidak dapat berdiri sendiri sehingga pengembangan nanokomposit menjadi penting dilakukan untuk menghasilkan material dengan sifat baru. Berdasarkan latar belakang permasalahan lingkungan dan energi, serta potensi nanoselulosa dan nanokarbon, pada naskah orasi ini disampaikan pemanfaatan nanokomposit berbasis nanoselulosa dan nanokarbon sebagai material fungsional. Bioselulosa mempunyai potensi besar sebagai kemasan yang ramah lingkungan untuk mengatasi permasalahan sampah plastik yang tidak dapat didegradasi secara alami. Sementara itu, nanokomposit CNT merupakan material fotokatalis dan support elektrokatalis yang dapat digunakan sebagai pengganti carbon black pada sel bahan bakar berbasis polimer. Naskah orasi ini memaparkan perkembangan iptek dan potensi nanoselulosa dan nanokarbon, pengembangan nanokomposit berbasis nanoselulosa dan nanokarbon, serta peluang pemanfaatan nanoselulosa dan nanokarbon di Indonesia, yang akan disampaikan pada Bab II–IV.

Downloads

Download data is not yet available.

Author Biography

Rike Yudianti, Badan Riset dan Inovasi Nasional

Pernah menduduki jabatan struktural sebagai Kepala Loka Penelitian Teknologi Bersih LIPI (2016–2017) dan Kepala Pusat Penelitian Fisika LIPI (2017−2021), kemudian dilanjutkan menjadi Pelaksana Tugas Kepala Pusat Riset Fisika, Organisasi Riset Ilmu Pengetahuan Teknik BRIN hingga saat ini.Jabatan fungsional peneliti diawali sebagai Asisten Peneliti Madya tahun 1997, Ajun Peneliti Muda 1999, Ajun Peneliti Madya 2004, Peneliti Ahli Madya 2009, dan Peneliti Ahli Utama 2017. Menghasilkan 85 karya tulis ilmiah, baik yang ditulis sendiri maupun bersama penulis lain, dalam bentuk buku, jurnal, prosiding, paten; dan 67 di antaranya dalam bahasa Inggris.
Ikut serta dalam pembinaan kader ilmiah, yaitu pembimbing skripsi (S1) pada Universitas Sumatera Utara, Universitas Islam Nusantara, Institut Teknologi Telkom, dan Universitas Ahmad Dahlan; pembimbingan tesis (S2) pada Institut Teknologi Bandung, Universitas Gajah Mada; pembimbingan disertasi S3 pada Universitas Indonesia, Institut Teknologi Bandung, dan Osaka University.

References

World Bank. Hotspot sampah laut Indonesia. Public Disclosure Authorized 2018; 1–49.

United Nations Department of Global Communications. Sustainable Development Goals 2020.

Sugiyono A. Outlook energi Indonesia 2015-2035. Prospek Energi Baru Terbarukan. J. Energi dan Lingkungan 2016; 12(2) : 87–96.

Indriyati, Yudianti R, Indrarti L. Development of bacterial cellulose / activated carbon composites prepared by in situ and cast-drying methods. Asian Transaction on Basic Applied Science 2012; 2(5) : 21–24.

Suhas SK, Gupta VK, Carrott PJM, Singh R, Chaudhary M. Cellulose: A review as natural, modified and activated carbon adsorbent. Bioresources Technology 2016; 26 : 1066–1076.

Azeredo HMC, Barud H, Farinas CS, Vasconcellos VM, Claro AM. Bacterial cellulose as a raw material for food and food packaging applications. Frontiers in Sustainable Food Systems 2019; 3 : 1–14, 2019.

Yudianti R, Karina M, Sakamoto M, Azuma J. Precise structure of acidic polysaccharide present in salvia hydrogels. Wood Scince Journal 2019; 1(2) : 95–102.

Martinez-Hernandez AL, Velasco-Santos C, Castano VM. Carbon nanotubes composites: processing, grafting and mechanical and thermal properties. Current Nanoscience 2010; 6(1) : 12–39.

Sabrina Q, Rina Ratri C, Hardiansyah A, Lestariningsih T, Subhan A, Rifai A, Yudianti R, Uyama H. Preparation and characterization of nanofibrous cellulose as solid polymer electrolyte for lithium-ion battery applications. RSC Advances 2021; 11(37) : 22929–22936.

Hon DNS. Cellulose : a random walk along its historical path. Cellulose 1994; 1 : 1-25.

Indrarti L, Yudianti R. Morphological and thermal properties of alkali treated bacterial cellulose from coconut water. Journal Sains Materi Indonesia 2012; 13 : 221–225.

Shim H, Karina M, Yudianti R, Indrarti L, Azuma J, Uyama H. One-sided surface modification of bacterial cellulose sheet as 2,3-dialdehyde. Polymer-Plastics Technology and Engineering 2015; 54 : 305–309.

Shim H, Karina M, Yudianti R, Indrarti L, Azuma J. One-dimensional shrinkage and swelling of crosslinked bacterial cellulose gel. Chemistry Letter 2016; 45 : 253–255.

Ross P, Mayer R, Benziman M. Cellulose biosynthesis and function in bacteria. Microbiological Reviews 1991; 55 : 35–58.

Delmer DP, Benzimantt M, Padan E. Requirement for a membrane potential for cellulose synthesis in intact cells of Acetobacter xylinum. Proceedings of the National Academy of Sciences 1982; 79 : 5282–5286.

Fang Z, Zhu H, Preston C, Han X. Highly transparent and writable wood all-cellulose hybrid nanostructured paper. Journal of Materials Chemistry C 2013; C 1 : 6191–6197.

Onggo H, Syampurwadi A, Yudianti R. Pembuatan gas diffusion electrode dengan teknik screen printing: pengaruh microporous layer terhadap strukturmikro dan kinerja elektrokatalis. Journal Sains Materi Indonesia 2013; 14(4) : 253–258.

Izumi R, Yao Y, Tsuda T, Torimoto T, Kuwabata S. Pt-Nanoparticle-supported carbon electrocatalysts functionalized with a protic ionic liquid and organic salt. Advanced Material Interfaces 2018; 5(3) : 1701123-1701128.

Iijima S. Helical microtubules of graphitic carbon. Nature 1991; 354 : 56–58.

Yudianti R, Azuma J. Studies on properties of cellulosic hydrogels in salvia nutlets: tiny soft treasures on earth. Lambert Academic Publishing ; 2012.

Nevell TP, Zeronian SH. Cellulose chemistry and its applications. John Wiley ;1987 : 140250212.

Iguchi M, Yamanaka S, Budhiono A. Bacterial cellulose: a masterpiece of nature’s arts. Journal Material Science 2000 ; 35 : 261–270.

Zeng M, Laromaine A. Bacterial cellulose films: influence of bacterial strain and drying route on film properties. Cellulose 2014; 21 : 4455–4469.

Klemm A, Heublein D, Fink B, Bohn. Cellulose: fascinating biopolymer and sustainable raw material. Angewandte Chemie International. 2005.

Yudianti R, Indrarti L, Azuma J. Structure and physical properties of natural gellous material. Journal of Applied Science 2007; 7(4) : 580–584.

Yudianti R, Indrarti L, Karina K, Sakamoto M, Azuma J. Chemical compositions of hydrocolloids produced from nutlets of salvias. Journal of Tropical Wood Science and Technology 2007; 5(1) : 12–16.

Yudianti R, Indrarti L, Sakamoto M, Azuma J. Cellulose-hemicellulose present in hydrocolloids from Salvia spp. in The Sixth International Wood Science Seminar, 2005.

Yudianti R, Karina M, Sakamoto M, Azuma J. Effects of salts on rheological behaviour of salvia hydrogels. Macromolecular Research 2009; 17 : 332–338.

Yudianti R, Karina M, Sakamoto M, Azuma J. DSC Analysis on water state of salvia hydrogels. Macromolecular Research 2009 ; 17(12) : 1015–1020.

Vysikaylo PI. Quantum size effects arising from nanocomposites physical doping with nanostructures having high electron affinity. Series Natural Sciences 2021 ; 3 : 150–175.

Roduner E. Size matters: Why nanomaterials are different. Chemical Society Reviews 2006 ; 35(7) : 583–592.

Karina M, Indrarti I, Yudianti R. Effect of castor oil impregnation on the physical and mechanical properties of bacterial cellulose. Polymer from Renewable Resources 2012; 3(1) : 13-26.

Iwata T, Indrarti L, Azuma J. Affinity of hemicellulose for cellulose produced by Acetobacter xylinum. Cellulose 1998; 5 : 215–228.

Karina M, Indrarti L, Yudianti R, Syampurwadi A. Alteration of bacterial cellulose properties by diacetylglycerol. Procedia Chemistry 2012 ; 4 : 268–274.

Yudianti R, Indrarti L. Effect of water soluble polymer on structure and mechanical properties of bacterial cellulose composites. Journal of Applied Science 2008 ; 8(1) : 177–180.

Iriani EI, Wahyuningsih K, Sunarti TC, Permana AW. Sintesis nanoselulosa dari serat nanas dan aplikasinya sebagai nanofiller pada film berbasis polivinil alkohol. Jurnal Penelitian Pascapanen Pertanian 2015 ; 12(1) : 11–19.

Karina M, Indrarti L, Yudianti R, Indriyati, Syampurwadi A, Widodo H. Impact of esterified palm oil impregnation on bacterial cellulose properties. Polymers from Renewable Resources 2012 ; 3(4) : 139-152.

Yudianti R, Syampurwadi A, Onggo H, Karina M, Uyama H, Azuma J. Properties of bacterial cellulose transparent film regenerated from dimethylacetamide–LiCl solution. Polymer Advanced Technologies 2016 ; 27 :1102–1107.

Yudianti R, Indrarti L, Onggo H. Thermal behavior of purified multi walled carbon nanotube. Journal of Applied Science 2010 ; 10(17) : 1978-1982.

Subagio A, Yudianti R, Rowi K, Taufiq MI. Pemurnian carbon nanotubes menggunakan larutan HNO3 dengan metode pencucian biasa dan reflux. Jurnal Fisika Indonesia 2014 ; 17 : 1–4.

Yudianti R, Onggo H, Sudirman, Saito Y, Iwata T, Azuma J. Analysis of functional group sited on multi-wall carbon nanotube surface. Open Material Science Journal 2011 ; 5(1) : 242–247.

Yudianti R, Oemry F, Indrarti I, Onggo H. Analysis of crushed multi-walled carbon nanotubes. Indonesian Journal of Material Science 2010 ; 11(2) : 99-102.

Yudianti R, Onggo H, Indriyati. Role of catalytic synthesis on growth and distribution of platinum nanoparticle on carbon nanotube surface. Nanoscience Nanotechnology 2012 ; 2(6) : 171–177.

Yudianti R, Onggo H, Syampurwadi A. Molecular conformation of nafion ionomer on electrocatalyst layer prepared by screen printing technique. International Journal of Electrochemistry Science 2014 ; 9 : 3047-3059.

Irmawati Y, Khaerudini DS, Indriyati, Mardiyati, Yudianti R. Dispersibility of multiwall carbon nanotube in a polyanionic surfactant based on UV-VIS analysis. Indonesian Journal of Chemistry 2020; 20(5) : 1206–1212.

Yudianti R, Hutabarat LG, Irmawati Y, Widodo H, Indayaningsih N, Magfirah A. Carbon nanotube network as an electron pathway in nanocomposite films. International Journal Material Research 2020; 111(3) : 197–203.

Fujigaya T, Nakashima N. Non-covalent polymer wrapping of carbon nanotubes and the role of wrapped polymers as functional dispersants. Science and Technology of Advanced Materials 2015; 024802 : 1-21.

Sudirman, Indriyati, Adi WR, Yudianti R, Budianto E. Structural analysis of platinum nanoparticles on carbon nanotube surface as electrocatalyst system. International Journal of Chemistry 2017; 9(2) : 60-65.

Jeng KT, Chien CC, Hsu NY, Yen SC, Chiao SD, Performance of direct methanol fuel cell using carbon nanotube-supported Pt-Ru anode catalyst with controlled composition. Journal Power Sources 2006; 160(1) : 97–104.

Sudirman, Adi A, Budianto E, Khaerudin DS, Yudianti R. Mono-Dispersed Pt/MWNTs: growing directly on multiwall carbon nanotubes (MWNTs) using NaBH4 as reducing agent for component of proton exchange membrane fuel cell (PEMFC). International Journal of Chemistry 2019; 12(1) : 37.

Irmawati Y, Indriyati, Onggo H, Yudianti R. Kajian kinerja polymer electrolyte membrane fuel cell open cathode terhadap variasi tegangan kipas katoda dan variasi laju alir hidrogen pengaruh kipas pada kinerja PEMFC open. Indonesia Material Science Journal 2012; 13 : 216–220.

Syampurwadi A, Onggo H, Indriyati, Yudianti R. Performance of PEM fuel cells stack as affected by number of cell and gas flow-rate. Journal of Physics Conference Series 2016; 755.

Sivakumar M, Towata A, Yasui K, Tuziuti K, Kozuka T, Iida Y. Ultrasonics sonochemistry dependence of sonochemical parameters on the platinization of rutile titania – An observation of a pronounced increase in photocatalytic efficiencies. Ultrason - Sonochemistry 2010; 17(3) : 621–627.

Tri Yulianti R, Irmawati Y, Destyorini D, Yudasari N, Syampurwadi A, Aryanto D, Isnaeni, Yudianti R. UV photoactivity of a flexible ZnO hybrid photocatalyst grown on a conductive cellulose-based substrate. AIP Conferrence Proceeding 2021.

Halim S. Revolusi Industri 4.0 di Indonesia. Interciencia 2018; 30(8) : 1.

Kudzai Mugadza VO, Stark A, Patrick G Ndungu, Nyamori. Synthesis of carbon nanomaterials from biomass utilizing ionic liquids for potential application in. Material 2020; 13 : 2–26.

Osman AI, Farrell C, Al-Muhtaseb AH, John A. Rooney W. The production and application of carbon nanomaterials from high alkali silicate herbaceous biomass. Nature Research 2020; 1–13.

Rimayanto Gintu. sintesis dan karakterisasi carbon nanotube ( CNT ) dari Arang Kayu Jati Serta Pemanfaatannya Sebagai Bahan Aktif Antibakteri. Jurnal Kimia Riset 2020; 5(2) : 127–133.

Destyorini F, Irmawati Y, Hardiansyah A, Widodo H, Dimas Yahya I, Indayaningsih N, Yudianti R, Hsu Y-I, Uyama H. Formation of nanostructured graphitic carbon from coconut waste via low-temperature catalytic graphitisation. Engineering Science and Technology, an International Journal 2021; 24(2) : 514–523.

Destyorini F, Yudianti R, Irmawati Y, Hardiansyah A, . Hsu, and H. Uyama. Temperature driven structural transition in the nickel-based catalytic graphitization of coconut coir. Diamond Relation Material 2021; 117 (108443) : 1-8.

Angelia M. Teknologi Fuel Cell, Alternatif Energi Listrik untuk BTS. http://tekno.liputan6.com/read/2304179/inikah-dampak-mematikan-pemanasan-global 2016.

Downloads

Published

March 9, 2022
HOW TO CITE

Details about this monograph

ISBN-13 (15)

978-623-7425-57-1